Product ID:02880, ETHANOL ABSOLUTE DENATURATED WITH (SUPDAT)
MSDS Date:10/01/1994
FSC:6810
NIIN:00N069822
MSDS Number: CBKWV

SIGMA CHEMICAL CO

ST LOUIS, MO 63178
US

Emergency Phone: 516-467-3535

Info Phone: 314-771-5765

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

(ORAL,RAT) 7060 MG/KG

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: NO

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED,
INHALED/ABSORBED THRU SKIN. VAP/MIST IS IRRITATING TO EYES, MUC
MEMB & UPPER RESP TRACT. CAUSES SKIN IRRIT. MAY CAUSE NERV SYS
DISTURB. EXPOS CAN CAUSE:NAUS, HDCH & VOMIT, NARCOTIC EFT, DMG TO
HEART, LUNG IRRIT,CHEST PAIN & EDEMA WHICH MAY BE FATAL.
CHRONIC:INHAL STUDIES (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:ON TOLUENE HAVE DEMONSTRATED
DEVELOPMENT OF INFLAMMATORY & ULCEROUS LESIONS OF PENIS, PREPUCE &
SCROTUM IN ANIMALS. TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM
REPROD HAZS. SEEK CONSULTATION F ROM APPROP HLTH PROFESSIONALS
CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . TARGET
ORGAN(S) (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES/SKIN:IMMED FLUSH WITH COPIOUS AMTS OF WATER FOR @ LEAST
15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. INHAL:REMOVE TO FRESH
AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG.
INGEST: WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL
PHYS. WASH CONTAMD CLTHG BEFORE REUSE.

Flash Point:48.0F,8.9C
Lower Limits:3.3%
Upper Limits:24.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
PVNT CONT W/SKIN & EYES. USE WATER SPRAY TO COOL FIRE-EXPOS
CONTAINERS. FLAMMABLE LIQUID.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CNDTNS. VAP
MAY TRAVEL CONSIDERABLE DIST TO SOURCE OF IGNIT & FLASH BACK.
CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.

Spill Release Procedures:SHUT OFF ALL SOURCE OF IGNIT. EVAC AREA. WEAR
NIOSH/MSHA APPRVD SCBA, RUBB BOOTS & HEAVY RUBB GLOVES. ABSORB ON
SAND/VERMICULITE & PLACE IN CLSD CNTNRS FOR DISP. USE NONSPK TOOLS.
VENTILATE AREA & WAS H SPILL SITE AFTER MATL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP TIGHTLY CLSD. KEEP AWAY FROM
HEAT, SPKS, & OPEN FLAME. STORE IN COOL DRY PLACE. IRRITANT. TOXIC.
READILY ABSORBED THRU SKIN. DO NOT BREATHE VAP.
Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLTHG. FLAMMABLE.
KEEP AWAY FROM SOURCES OF IGNIT. NO SMOKING. IN CASE OF ACCIDENT OR
IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW THE LABEL WHERE
POSS).

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPRVD RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:RUBBER BOOTS. ANSI APPRVD EMER EYE WASH &
DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:1% TOLUENE, 02880. EFTS OF OVEREXP:NERVES,
LIVER, BRAIN, KIDNEYS, BLADDER.

Vapor Pres:44.6 @ 20C
Vapor Density:1.59
Spec Gravity:0.789
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:LIQUID.

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, PEROXIDES, ACIDS, ACID CHLORIDES, ACID ANHYDRIDES,
ALKALI METALS, AMMONIA.
Stability Condition to Avoid:PROTECT FROM MOISTURE.
Hazardous Decomposition Products:TOXIC FUMES OF:CARBON MONOXIDE, CARBON
DIOXIDE.

Waste Disposal Methods:BURN IN A CHEM INCIN EQUIPPED WITH AN
AFTERBURNER & SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

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particular situation.